From Web site of Chris Caldwell at UTM.
Note a lot more info is there...type in "is one a prime number" into google. This is a short help.
There was a time that many folks defined one to be a prime, but it is the importance of units and primes in modern mathematics that causes us to be much more careful with the number one (and with primes). When we only consider the positive integers, the role of one as a unit is blurred with its role as an identity; however, as we look at other number rings (a technical term for systems in which we can add, subtract and multiply), we see that the class of units is of fundamental importance and they must be found before we can even define the notion of a prime. For example, here is how Borevich and Shafarevich define prime number in their classic text "Number Theory:"
An element p of the ring D, nonzero and not a unit, is called prime if it can not be decomposed into factors p=ab, neither of which is a unit in D.
Sometimes numbers with this property are called irreducible and then the name prime is reserved for those numbers which when they divide a product ab, must divide a or b (these classes are the same for the ordinary integers--but not always in more general systems). Nevertheless, the units are a necessary precursors to the primes, and one falls in the class of units, not primes.
Cheers