If all the other radiators are hot, this suggests the system needs BALANCING. This means forcing enough water through all the pipes that lead to the rads. The very act of doing this may lead to the need for a more powerful pump as Stuelwell suggests.
I haven't a clue what Parkesquay is referring to, but it doesn't seem relevant to me.
To balance the rads to adjust the lockshield valves on the opposite end of the rads to the adjustment (normally TRVs these days). It is behind the scope of this site to explain in a few words how to do it.