Easy peasy Dave........... especially for a Devon lad ...........
Switch off at the switch, and to be sure, off at the circuit breaker as well.
Take off cover
Unscrew the 2 wires attached to thermostat
Pull stat out
Reverse procedure
I would add you will need a spanner to remove the thermostat the best ones are like a big socket they are expensive to buy you can hire them quiet cheap if you buy a cheap ring spanner type you will have to be carefull how much force you use ,you can kink the copper tank.
can you tell me how to drain my heater tank, have turned off water supply and turned on all hot taps but tank has still not emptied and when I tried to remove the thermostat water started to pour out of the apperture. So had to replace old thermostat to stop water Any help greatly accepted