The is a different question to the one you asked last Saturday, as your roof space has now apparently sprouted a former window, which you didn't mention before.
Sure, as TB says, you can insulate the sloping surfaces so as to make the enclosed roof space part of the "thermal element" of your house. You would have to do that to meet Building Regulations to be able to use the space as a habitable room.
The problem is getting enough insulation into the sloping void. You will almost certainly need half of the thickness of whatever fibreglass you were told to put over the boarding floor, but using rigid insulation board like Celotex. The reason for this is because the insulating properties of this board are 2x the performance of fibreglass. You may just have enough depth on the sloping depth of the timber trusses to do that.
However this solution will not be adequate if you converted the space into a room because the insulation already under the floor becomes useless as part of an external insulating shell around the warm house, if you have made the loft a part of that warm shell.
In that case you have to use a combination of rigid foam and multifoil insulation. This foil is very expensive but worth it for those doing loft conversions.
This is not a DIY job and you need paid for advice from someone who can survey onsite.
You certainty won't qualify for grants for this, it is a home improvement project.