Ok Here goes,
Nip down to your local DIY shop or Plumbers merchant and buy a bottle of 'BetzDearborn' Sentinel X200 boiler de-scaler �12.99 ish. It Restores Boiler Efficiency and Eliminates Kettling, (Which is what i suspect you have). Then turn off your boiler and with a rad key let out all the pressure by slackening the vent nipple on the highest rad (usually the towel rad in the bathroom if you have one) use a suitable container & a cloth to catch the water, if you have carpet down then make sure you put down a suitable protective covering as any spills will permanently stain. When it stops flowing all the pressure will have gone and it will be safe to open up the system.
Now put a suitable container underneath the draw off point fitted to your system it will prob be at the lowest point in the pipe work and also some under your boiler aswell. ( these are the small brass valves that have a ringed spout that you can attach a hose pipe to ). Turn the square lug that is on the end of it using a suitable tool ( small adjustable or pliers / grips ) anti clockwise to open it up and let out some of the fluid from your system. Not too much at this point just say five litres or so. If you cannot get a tub under it then attach a small length of hosepipe to it and run it into a mop bucket or somthing similar. Then tighten it back up again.