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Right here we go: - Go in to limewire, go to your libary & select audio. Once all your songs appear highlight them all using your shift & cursor. Once you have selected them all then click on Enqueue - all your songs will then be in the bottom of your screen as well as the top.
Once they are there, click on 'save as' (below) I saved mine as Limewire260107 (so you have the date and can resave later on when you have more music to add) this was then automatically saved in your documents in my music.
When I went back into i-tunes, I clicked on HP-ownerLimewire tunes and they are all there - once you plug your ipod into the pc - click on file & update ipod.
It worked really fast and you can see at the top of the i-tunes screen it says that it is updating it and you can see song by song which one is going over.
Good luck!!! Really hope this helps :-) xx