Firstly, ignore the 3.5A figure. It tells you the maximum current that the adapter can safely supply to a device attached to it. Since you'll have nothing attached to the adapter (other than the meter), this figure is completely irrelevant.
What you need to check is the voltage supplied by the adapter. The phrase 'AC adapter' is loosely used to describe both something which simply drops the mains voltage down to (in your case) 18.5V but keeps it as an AC current OR something which drops the voltage to 18.5V but also converts it to DC. You need to know what it is that your adapter is designed to do.
If you're not sure whether the output is AC or DC, read the label to see if it tells you. If it doesn't actually say 'AC' or 'DC', it might use symbols. A wavy line like this ~ means AC. A solid line with a dotted line above or below it means DC.
If you decide that you're measuring an AC voltage, use the socket labelled V~. If it's DC, use V--.
Set the dial to the lowest voltage which is above 18.5V. So, for example, if your choice is 10V, 50V or 250V, you'd choose 50V (and then read the scale which runs from 0 to 50 to find out what the output of the adapter is).
Chris