I am now going to try and pull together all my answers to try and help you understand how to do these type of problems.
There are three variables (M,W,C) and only 2 equations possible, therefore you do not have enough information to solve just by using simultaneous equations.....but
You now look at what further information you can glean. Here the only variable denominated in pence is the cost of the children. To get whole numbers of people, it therefore follows that the volume of children can only be in units of 20, to ensure whole pounds. Otherwise the cost cannot be exactly 100 pounds.
As you know there must be some men, some women and some children, you can disregard solutions where there are no children or 100 children.
Therefore the only possible solutions will be where there are 20, 40, 60 or 80 children.
It is now necessary to go through these 4 scenarios in turn and see if they produce a solution. NO OTHER SOLUTIONS apart from these 4 scenarios are possible
Assuming C = 20 (cost 20 x 0.05 = 1 pound)
This leaves 100 - 20 = 80 people costing 100 - 1 = 99 pounds
Now set up simultaneous equations
M + W = 80
5M + W = 99 (men 5 pounds, women 1 pound)
Subtract top equation from bottom)
4M = 19
M = 4.75
As it is impossible to have 3/4 of a man, you can reject the scenario where C = 20
Do the same for C = 40, cost C = 40 x 0.05 = 2 pounds
M + W = 60 (ie 100 - 40)
5M + W = 98 pounds
Subtract top from bottom
4M = 38
M = 9.5
As you can't have half a man, reject the scenario where C = 40
Now C = 60, cost = 60 x 0.05 = 3 pounds
M + W = 40
5M + W = 97
Subtract top from bottom
4M = 57
M = 14.25
As you can't have 1/4 of a man reject this scenario where C = 60
Final possible solution where C = 80, cost = 80 x 0.05 = 4 pounds
M + W = 20 (ie 100 - 80)
5M + W = 96 (ie 100 - 4 pounds)
Subtract top from bottom
4M = 76
M = 19 ...hooray a solution
As M + W = 20 and M = 19 it follows that W = 1
Therefore the ONLY solution is
M = 19, W = 1 and C = 80
Check the values
M = 19 x 5 = 95 pounds
W = 1 x 1 = 1 pound
C = 80 x 0.05 = 4 pounds
Total people = 19 + 1 + 80 =100
Total cost = 95 + 1 + 4 = 100 pounds
Solution correct
and as we went through the only other three possibilities that could yield a solution, and ruled them out, we conclude that this is a UNIQUE solution.