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How many letters and do you have any placed ?

Pumice ?
Black smokers? (I googled your clue)

Where is this crossword from please (if it is a crossword)?. That helps us to know the style of the setters.
Sal Ammoniac?
Times 2 Jumbo, 49a Mineral often condensing near volcanic vents Answer- Sal ammoniac

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mineral volcano vents

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