For all you non-believers:
http://forums.xkcd.com/viewtopic.php?f=3&t=311
The following is an extract copied from the above thread:
(it assumes that the first child is a boy, rather than a girl - so just switch everything round)
The question doesn't specify how you know one of the children is a boy. If you grabbed the first child and looked at its genitals, and it happened to be a boy, then the chances that the second child is a girl are 50%, since it's an independent question. If, on the other hand, all the question is saying is that you checked to see if there was a boy in the pair, that's a different question. It implies you checked the first child, and if it was a girl, then you went on to check the second. In that case, the probability that one of the children is a girl is 2/3.
You can think of it this way: You know you found a boy. Either the first child you checked was a boy, or the first child was a girl and the second was a boy. Given the three possibilities (b-b, b-g, and g-b), all with equal probability, there is a 2/3 probability that the first child you checked was a boy. So 2/3 of the time there's a 50% chance the second child is a girl, plus the 1/3 of the time the first child is certainly a girl, for a total of 2/3 of the time one of the children is a girl.
............ continued in next post .........