Question Author
Marty - thanks, yes, it is a matter of rules.
(We are considering games with just two players.) With no spinning of the cylinder between rounds, I reckon each player has an equal chance of dying (or surviving). After the cylinder has been spun at the start, the chances of the bullet being being in an "odd" chamber are the same as it being in an "even", therefore the first player has the same chance of shooting himself as the second. (Same conclusion as Dr b above, by a different route.)
I now realise that this does not agree with the book answers because they assume spinning the cylinder between firings, in which case the chances of the two players are not equal. I'm not sure that I follow the reasoning fully, I'll have to study it before posting anything (not helped with death being considered "victory"). I think I've been through this before, but forgot whaat I learnt! Thanks for all contributions so far.