MrsProf recently had one of these fitted in our kitchen - I should have guessed what would happen when she followed my PA into the lab kitchen to make a coffee and saw one for herself!
Anyway, I can confirm that water does come out of the tap at as close to 100 degrees C as makes no difference for domestic use. I've bunged a specialised standardised thermometer beneath the stream and it comes up with a consistent reading of 99.99999998 C which you can safely regard as being the closest to boiling water as you'll ever actually need.
Before I saw the lab Quooker working, I thought that if this device didn't serve as a severe scalding hazard, nothing would. However, all the models release the water as a spray from the outlet rather than what you are accustomed to from a tap. The flow mechanism is completely childproof.
The tank beneath the sink holds 3 litres of water and uses about 10W of power in standby mode. The heater itself is rated at about 1600W.
The bad news is that although Quooker and currently running a free installation scheme, the complete set-up will not give you much change from around £900.
All the same, it does make lovely tea first thing in the morning!