The reason that micro-black holes are interesting is that Stephen Hawking famously predicted that black holes should slowly evaporate. However testing that is pretty much impossible with an astronomical black hole. If you could create a micro black hole it should evaporate very quickly and we could see if this was true or false and we'd learn quite a bit about some quite important stuff to do with how the Universe is stitched together.
But as Kempie says that's not actually what the LHC at CERN is trying to do. They're looking for the Higgs particle. This is a particle which is predicted to explain why all the others have mass.
When this experiment was looking for funding the Science Minister William Waldegrave set a competition to explain on a side of A4 "What is the Higgs particle and why should we want to find it" the prize was a case of champagne.
The winner used the analogy of the Margaret Thatcher walking through a cocktail party with hangers on temporarily sticking to her.
As for electrons there are uncountable billions of them every atom contains them. Although they have an infinitessimal mass they have no physical size or at least not that we can measure.
For anybody interested here's a neat although moderately technical explanation of why an electron is probably not a black hole
http://physlink.com/Education/AskExperts/ae191 .cfm