Wind Chill is really a measure of the rate at which heat energy is removed from the human body. For instance at an air temperature of 4 Celsius it would be quite comfortable to go for a walk in light clothing if there was no wind. However, it it was windy it would feel much colder because the moving cold air would remove heat energy from your body much quicker.
Rainwater or condensation (dew) is impure and will freeze at zero Celsius. Irrespective of the windchill factor, for water to freeze the actual air temperature must be at or below zero Celsius.