Regardless of what your controls say, is your room overheating? If not, then probably the boiler is making sure your hot water is ready and waiting within the boiler, radiating heat unnecessarily, just on the off-chance that you might turn a hot tap on. If you can figure it out from your instructions, you might prefer to make the hot water supply only available when you turn on a tap, rather than sitting there giving off unnecessary heat into the room. If your lifestyle suits the hot water being there all the time, then stay with it; but give it some thought.