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For more on marking an answer as the "Best Answer", please visit our FAQ.Ultra-violet light liberates Chlorine from them in free radicals and this breaks up Ozone. ( I won't say catalyses because last time I did there was a very long and complex discussion about whether or not it was a true catalytic reaction).
Have a look here anyway:
http://en.wikipedia.org/wiki/Ozone_Depletion
As for getting up there, there is a complicated climatic set of circumstances that is particularly prevalent over the South Pole. This forms a polar vortex in which ozone depletion is most pronounced:
http://en.wikipedia.org/wiki/Polar_vortex
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