For a diagnosis you really need to be more precise on exactly what's happening and when. As a general gude, however, an old style diesel will chuck out three types of smoke, which all mean something different.
White smoke on start-up is normal, it's unburnt fuel that's pumped out of the combustion chambers before the engine fires: once it starts to run on all cylinders it stops smoking. Faulty glowplugs will cause this to go on for some time, however, as the engine catches, stalls, catches, over and over as it struggles to start without preheating.
Black smoke as you accelerate is caused by overfuelling: basically too much diesel is being burned, more than you need, and the usual cause of this is either a blocked air filter or leaking and dripping injectors which are too worn to close properly, it's also sometimes caused by misguided attempts at increasing performance by turning the fuelling up: it doesn't work unless more air is pushed in as well, which is what turbos are for....
Blue smoke is burnt engine oil, caused by a worn engine.
If you only have a problem at start up and for the first few minutes, this would point to faulty glowplugs or a faulty relay, or possibly air getting into the system: does it help if you prime the pump before starting?
Leave the injectors well alone. You only need to do anything with them if there is BLACK smoke under acceleration or, in bad cases, normal running. Don't be tempted to get them out and fiddle with them, they are precision instruments, there is nothing you can do with them on a DIY basis. If they are shot, you need to get them reconned professionally, �100 to �150 for all four- good value really as you only need to do it every 150000 to 200000 miles.
If you are talking about a common rail system however, you have the electronics to contend with as well which is a different ball game again!