Overhead power lines have a core of steel wires for strength surrounded by aluminium wires for conductivity.
Underground cables, where they are practicable, have copper, which is a better conductor than aluminium, as a core. This reduces heat losses which don't matter overhead because the air acts as a coolant but is a problem underground.
High voltage underground cables also have to masses of insulation (again supplied by the atmosphere when overhead) plus electric and magnetic screens to reduce interference. The core has a hole through its centre to allow cooling oil to be pumped through.