Hi Alba
havbe just noticed your Q and no-one has given you the correct answer, though the answer about leaks go part way.
Water is rarely neutral. Its pH may be one way or the other, and so it acts as an electrolyte and you get a very tiny amount of inter-reaction between the copper, brass and the iron in your boiler and rads. This causes gases to be given off, usually hydrogen and oxygen, but you are unlikely to get a stoicometric reaction, as there is no spark, so just let out the gas from the highest rad, and refill the system to about 0.5 bar, looking at the gauge on your boiler. Make sure you keep the rads free of air (gases) by monthly checking with a bleeding key. No, a key for bleeding.
Good luck.
Paul