Boy, this one's a real stinker this week as every answer I get doesn't match what I hold for the questions I have left and the answers I've worked out for the other clues.
13a Gerenrous (7) L???R?L (I have liberal, but this means either Amsterdam or Rotterdam is wrong)
14d Conceited (3,6) ??? / ?E?D?? (I was told Big Headed earlier but this means Regimen is wrong)
25a Wrongd (9) ????R?A?? ( I have Miscreant, but this means Big Headed is wrong)