I'd be wary for the moment about taking any active measures to reverse the concentrations of CO2 or combat the Greenhouse Effect. Far better action, at least for now, would be to reduce the amount we pump into the atmosphere every year and to stop or cut back significantly on other activities that harm the environment. Any active measures do indeed carry their own risks, and the rewards are uncertain. In the last few years we've seen that increasing greenhouse gas emissions don't necessarily translate into consistent global temperature rises. It ought to follow that "anti-greenhouse" materials won't necessarily lower the temperature either, or will lower it at a far greater rate than could have been anticipated.
There is plenty that can be done still before resorting to something like the proposal above.