Rad sizing depends on a couple of things, Sycamore. The size (volume) of each room, and the level of insulation.
Your existing rads, even if they're singles, may possibly already be the right size. i.e. the right surface area to radiate heat.
If the rads are old enough, there is a very good case for upgrading them though. Modern ones are high output, and much more efficient. TRVs (thermo rad valves) are always a good upgrade for efficiency.
One rad on the system is usually left without a TRV. It's simply a "heat leak" to carry away excess heat when all other rads are shut down or just not calling for heat. This is to keep the boiler healthy, mostly.
So, the short answer to your question is........... maybe. You really do need to calculate your sizing requirements first.
Something like this will tell you how much energy you need for each room. From that you look up the heat output of any rad to see if it's the right one.
http://www.diy.com/help-advice/btu-radiator-calculator/Dev_npcart_100006.art