3. She surprised many (5.5)
15. An old TV programme (3.5)
19. Sounds like a dark hat (10)
46. Complaint caused by vibration (5.6)
59. Bridge bidding sequence (9)
I don't know the details of this quiz. Do all answers have to contain the words 'black' or 'white'?
But, whatever .. I think Emeritus's answer of black ice is more likely to be right than white van.