You have air locks in your system. To get rid of them, you need to 'bleed' your radiators. Any hardware store will sell you a bleed key, and explain how to use it. It's very simple - you simply open the valve of each radiator to let the air out, but be careful, when the air has all been bled, water follows, so be ready to shut the valve quickly, and make surew you have an old cloth between the valve and the wall to avoid dirty water staining your paint or paper. Start on the ground floor, work your way up, and make the bathroom radiator, if you have one, the last one - if not, make it the radiator nearest the hot water tank. You may need to do this a couple of times, with a few days in between, but it should solve the problem.