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No best answer has yet been selected by kahunabean. Once a best answer has been selected, it will be shown here.
For more on marking an answer as the "Best Answer", please visit our FAQ.I've often wondered about this myself. Tyres often go pop, I suppose simply because they can quickly become exposed to direct heat impingement which not only weakens the integrity of the tyre but also heats the air inside it causing it to expand and eventually burst.
I feel sure there will be built in safeguards to prevent the petrol tank from rupturing due to heat. I would imagine there will be a maximum amount of petrol you can put into a tank even when full which will allow some space for expansion of the fuel due to heating and I'm sure there will also be some sort of relief valve which can reduce pressure but in normal circumstances poses no danger.
You're right in saying you need a petrol/air mix, but if the tank did rupture and petrol escaped it is almost certain that somewhere near the spillage the correct mixture would be present, and obviously with a source of ignition so close ignition would almost definitely occur. It may be, however that because it is only the petrol and air that is in the correct mixture that will ignite it may only show as a sudden flare up of flame (which I have seen many many times) and nothing on the scale of a Hollywood style explosion.