Your VCR was designed to record signals from the output of its built-in (analogue) tuner. You need to bypass that tuner by getting the VCR to record from the Scart input. You seem to have worked out how to do that, by setting it to record from 'LV2'. (Although that's a new label to me. The relevant button is usually labelled 'AV', 'AV1'. 'AV2', Line', Line In', 'Ext', 'Aux', etc).
If you're sure that the Scart lead from the TV is still plugged into the same socket (on the VCR) as the Freeview box was connected to, and you're also sure that you're still trying to record from the same 'channel' on the VCR, it's obvious that the correct signal can't be coming through the Scart lead.
Firstly, of course, remember that the TV will need to be switched on in order to record from Freeview. (If you turn it off you'll be turning off the only digital tuner in your set-up). Then check the manual for the TV to see what the two Scart sockets are meant to do. It might be that they're only able to accept incoming signals (e.g. the ouptuts from DVD players or from PlayStations). If so, you won't be able to record from the tuner which is built into the TV. Alternatively it might be that only one of the Scart sockets can provide an outut signal from the TV's tuner. (In which case, ensure that the lead is connected to the correct socket).
Remember that, as with your Freeview box, you've still only got one digital tuner in your set-up (unless you re-introduce the Freeview box, which can make things rather complicated), so you still won't be able to watch one Freeview channel while recording from another. (You'll need a recording device, such as a DVD recorder or PVR, with its own built-in tuner in order to be able to do that.
Chris