I'm not sure they're even 96% accurate.
According to wikipedia:
"While some people believe that polygraph tests are reliable, there is little scientific evidence to support this claim. For example, while some claim the test to be accurate in 90% - 95% of the cases, critics charge that rather than a "test", the method amounts to an inherently unstandardizable interrogation technique whose accuracy cannot be established. A 1997 survey of 421 psychologists estimated the test's average validity at about 61%, a little better than chance."