According to the TOTP website, the first episode broadcast on 1st Jan 1964 was presented by Jimmy Savile & Alan Freeman and contained the following acts:
� Cliff Richard & The Shadows (No title listed) (Promo Video)
� Dave Clark 5 "Glad All Over" (Performance)
� Dusty Springfield "I Only Want To Be With You" (Performance)
� Freddie & The Dreamers "You Were Made For Me" (Promo Video)
� Gene Pitney "24 Hours From Tulsa" (Performance)
� Swinging Blue Jeans "Hippy Hippy Shake" (Performance)
� The Beatles "She Loves You" (Disc)
� The Beatles "I Want To Hold Your Hand" (Promo Video)
� The Hollies "Stay" (Performance)
Unfortunately they are listed alphabetically.
http://www.bbc.co.uk/cgi-bin/totpperf/search.p l?type=totp1&mode=advanced
...and then there is this playlist from TV.com:
� Rolling Stones - I Wanna Be Your Man [Performance]
� The Hollies - Stay [Performance]
� Dusty Springfield - I Only Want To Be With You [Performance]
� Swinging Blue Jeans - Hippy Hippy Shake [Performance]
� Dave Clark 5 - Glad All Over [Performance]
� Gene Pitney - 24 Hours From Tulsa [Audience Dancing]
� Freddie & The Dreamers - You Were Made For Me [Film Sequence]
� The Beatles - I Want To Hold Your Hand [News Footage]
http://www.tv.com/top-of-the-pops-uk/1st-janua ry-1964/episode/122942/summary.html