A combi boiler uses a ''closed system'', meaning that as the water heats up and expands, there could be nowhere for the water expansion to go. So the expansion is taken up by an ''expansion vessel''. This is a small cylindrical tank inside the boiler. One half is connected to and filled with water from the heating system and the other half is filled with air under pressure. There's a flexible diaphragm between the two halves. It's not uncommon for a leak to develop in this diaphragm, and a continual drop in pressure with no signs of a leak from pipes or radiators is a symptom of this. If that's what it is, a new expansion vessel is the only answer.