Bhg481:
Physics was a subsidiary subject for my degree, so I did consider the errors that might creep into such an experiment. I actually worked the other way round though, starting with a hot kettle each time in order to maintain consistency (simply because I couldn't be bothered to wait for it to cool down).
I'm also aware that, to do the experiment with proper scientific rigour, I should have repeated each trial several time and then taken the mean of the figures I'd obtained. However, for the purposes of providing an answer here on AB, I viewed a single trial as acceptable.
BTW: I've just calculated the cost of boiling a single 'large mug' of water to be 0.86p based upon a typical electricity tariff.